- Keneitsino Lydia
- March 11, 2026
Best Radioactive Decay Time Problems MCQs Class 12 to Master Exam Concepts Fast
The rate equation for a reaction A→BA \rightarrow B is r=k[A]0r = k[A]^0. If the initial concentration of the reactant is a mol dm−3a\; mol\,dm^{-3}, the half-life period of the reaction is:
A. a/2ka/2k
B. aa
C. a/ka/k
D. 2a2a
Answer: A
Q2.
Half-lives of a first order and a zero order reactions are same. Then the ratio of the initial rate of first order reaction to that of zero order reaction is:
A. 1/0.6931/0.693
B. 2×0.6932 \times 0.693
C. 0.6930.693
D. 22
Answer: B
Q3.
The rate of a first order reaction is 1.5×10−2 mol L−1 min−11.5 \times 10^{-2}\; mol\,L^{-1}\,min^{-1} at 0.5 M concentration of the reactant. The half-life of the reaction is:
A. 0.383 min
B. 23.1 min
C. 8.73 min
D. 75.3 min
Answer: B
Q4.
Which condition among the following holds true at the stage of half-completion for the reaction A⇌BA \rightleftharpoons B?
A. ΔG°<0ΔG° < 0
B. ΔG°>0ΔG° > 0
C. ΔG°=0ΔG° = 0
D. ΔG°≠0ΔG° ≠ 0
Answer: B
Q5.
A and B decompose via first order kinetics with half-lives 54 min and 18 min respectively. Starting from an equimolar mixture, the time taken for the concentration of A to become 16 times that of B is:
A. 4.5 min
B. 2.25 min
C. 100 min
D. 108 min
Answer: D
Q6.
If the rate constant for a first order reaction is kk, then the time required for completion of 80% of the reaction is:
A. 3.2/k3.2/k
B. 1.6/k1.6/k
C. 4.8/k4.8/k
D. 0.8/k0.8/k
Answer: B
Q7.
For a reaction, the initial rate is R0=k[A0]2[B0]R_0 = k[A_0]^2[B_0]. By what factor will the rate increase if A becomes 1.5 times and B becomes 3 times?
A. 4.5
B. 3
C. 6.75
D. 2
Answer: C
Q8.
The half-life of a first order reaction is 60 minutes. If initial reactant amount is 50 g, the amount left after 4 hours is:
A. 6.25 g
B. 12.5 g
C. 3.125 g
D. 1.25 g
Answer: C
Q9.
For the elementary reaction X→Y+ZX \rightarrow Y + Z, the half-life is 10 minutes. Time required for concentration to reduce to 10% is:
A. 20 min
B. 33.2 min
C. 15 min
D. 25.2 min
Answer: B
Q10.
Sucrose hydrolyses in acid solution following first order kinetics with half-life 3.33 h. After 9 h, value of log10(1/f)log_{10}(1/f) is:
A. 81 ×10⁻²
B. 90 ×10⁻²
C. 9 ×10⁻²
D. 8 ×10⁻²
Answer: A
Q11.
A reaction has half-life of 1 minute. Time required for 99.9% completion is:
A. 10 min
B. 11 min
C. 13 min
D. 12 min
Answer: A
Q12.
For the first order reaction A→2BA \rightarrow 2B, 1 mole of A gives 0.2 mole of B after 100 min. The half-life is:
A. 693 min
B. 700 min
C. 793 min
D. 600 min
Answer: A
Q13.
Half-life of a substance is 36 minutes. If initial amount is 10 g, amount left after 2 hours is:
A. 1 g
B. 2 g
C. 3 g
D. 4 g
Answer: A
Q14.
Time taken for 12.8 g of radioactive substance to decay to 0.4 g (half-life = 138 s) is:
A. 720 s
B. 690 s
C. 245 s
D. 69 s
Answer: B
Q15.
For a first order reaction, the rate decreases from 0.04 to 0.01 between 10 min and 30 min. The half-life is:
A. 4 min
B. 8 min
C. 6 min
D. 2 min
Answer: C
Q16.
If a first order reaction is 80% complete in 60 minutes, the half-life is:
A. 16 min
B. 42 min
C. 25.85 min
D. 14.28 min
Answer: C
Q17.
In a concentration vs time graph for reaction A→BA → B, the point where curves intersect represents:
A. t1/2t_{1/2}
B. t1/4t_{1/4}
C. t2/3t_{2/3}
D. None
Answer: A
Q18.
When initial concentration doubles, the half-life of a zero-order reaction:
A. Is halved
B. Is doubled
C. Remains same
D. Tripled
Answer: B
Q19.
For first order decomposition of CH₃CHO, if initial pressure is 80 mm Hg and total pressure after 20 min is 120 mm Hg, half-life is:
A. 80 min
B. 20 min
C. 40 min
D. 10 min
Answer: B
Q20.
20% of a first order reaction completed at 10 AM and 20% remaining at 11:30 AM. Half-life is:
A. 90 min
B. 60 min
C. 45 min
D. 30 min
Answer: C
Q21.
Half-life of radioactive substance is 15 min. Amount decayed from 50 g after 1 hour is:
A. 37.5 g
B. 28 g
C. 46.875 g
D. 25 g
Answer: C
Q22.
The two-third life of first order reaction with k=5.48×10−14s−1k = 5.48 ×10^{-14} s^{-1} is:
A. 2.3035.48×10−14log3\frac{2.303}{5.48×10^{-14}} \log3
B. 2.3035.48×10−14log2\frac{2.303}{5.48×10^{-14}} \log2
C. 2.3035.48×10−14log(1/3)\frac{2.303}{5.48×10^{-14}} \log(1/3)
D. 2.3035.48×10−14log(1/2)\frac{2.303}{5.48×10^{-14}} \log(1/2)
Answer: A
Q23.
For first order reaction with rate constant 7×10−4s−17×10^{-4}s^{-1}, the half-life is:
A. 990 s
B. 79.2 s
C. 1237 s
D. 1.01×1051.01×10^5 s
Answer: A
Q24.
For reaction A→ProductsA → Products, half-life doubles when concentration halves. Order is:
A. Zero
B. One
C. Two
D. 0.5
Answer: C
Q25.
Rate constant = 4×10−3molL−1min−14×10^{-3} mol L^{-1} min^{-1}. Initial concentration = 2×10−22×10^{-2}. Half-life (seconds) is:
A. 300
B. 150
C. 180
D. 240
Answer: B
Q26.
Half-life of first order reaction = 60 min. Percentage left after 240 min is:
A. 6.25%
B. 4.25%
C. 5%
D. 6%
Answer: A
Q27.
Relation between half-life and rate constant for first order reaction is:
A. t1/2=0.693/kt_{1/2} = 0.693/k
B. t1/2=0.693kt_{1/2} = 0.693k
C. t1/2=kt_{1/2} = k
D. None
Answer: A
Q28.
A first order reaction is one-fifth completed in 40 minutes. Time for 100% completion is:
A. 100 min
B. 200 min
C. 350 min
D. Infinity
Answer: D
Q29.
If 90% completion time = t, then time for 99% completion is:
A. 2t
B. 3t
C. 4t
D. t
Answer: A
Q30.
Half-life of first order reaction = 10 min. Initial concentration = 12 M. Rate after 20 min is:
A. 0.0693 M min⁻¹
B. 0.693 M min⁻¹
C. 0.0693×30.0693 × 3 M min⁻¹
D. 0.0693×40.0693 × 4 M min⁻¹
Answer: C

Conclusion on Radioactive Decay Time Problems MCQs Class 12
In conclusion, radioactive decay is a fundamental concept that combines principles of nuclear chemistry and chemical kinetics. Mastering decay equations, half-life calculations, and decay constants is essential for success in chemistry examinations. Regular practice through Radioactive Decay Time Problems MCQs Class 12 enables aspirants to build strong conceptual understanding and improve numerical problem-solving skills. By consistently working on Radioactive Decay Time Problems MCQs Class 12, aspirants can develop confidence in solving complex decay calculations and perform well in both board and competitive examinations.